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Solvent Extraction
Detailed Introduction
Manufacturing Process
Design Features
Safety Features
Highlights
 
Safety in Solvent Extraction Plant

Every industry has potential hazards associated with it. Solvent Erection industry is no exception. There are three areas where potential hazards exist.
These are:
Mechanical accidents
Accidents due to the nature of raw materials, products & chemicals handled in the industry
Accidents due to the human failure.

It is the intention of this write-up to examine in detail these potential hazards with respect to the solvent extraction plant.


Mechanical Accidents

Accidents of this type occur mainly due to a machine which is in motion.
The drives of all the machines are a potential threat for accidents. A moving belt can break and fly and hit a person in the vicinity. Accidental insertion of hand or foot between a driving chain and chain wheel or between two gears will result in serious casualty. Therefore, insist upon covering the moving parts of a driving mechanism with properly designed guards.
Moving parts of some machines themselves are potential threat for accidents. Moving screw of a screw conveyor or moving chain of a chain conveyor can cause accidents in case they are not properly covered. Similarly moving chain or belt of bucket elevator or moving screw lift are potentials threats for accidents.
A frequent accident spot in the preparatory section of a solvent extraction plant is the space between two moving rolls of a cracker or a flaker. Several operators have lost their fingers by inserting a hand in these to catch a flying nut or bolt or stone which has come along with the feed material. Insist upon closing the cover of the machine when it is running so that the operator is not tempted to insert his hand.
The innocent looking rotary valve in an extraction plant can be a deadly source of accident. Many operators have lost their arms by inserting their hand in the rotor of the moving rotary valve. Therefore, the chutes at the feed and discharge ends of a rotary valve should be long enough so that a person cannot reach the moving rotor by inserting his hand.
The inspection doors in a hopper or chute of any machine shall be so located that it is far enough from the moving part of machine so that the hand inserted through this door cannot reach the moving part.
All machines with moving parts shall be provided with safety switches for their motors. Thus when a machine is under repair or maintenance its safety switch shall be in `OFF' position, so that the motor cannot be started by anybody accidentally pushing the starter button.
A main safety switch in each operating floor of a plant and preparatory and bagging sections shall be installed to switch off the entire plant in case of an emergency at any part of the plant.
Incidents of personnel in a plant getting electrical shocks are well known. This happens generally due to the incompetent people meddling with electrical equipment such as starters, fuses etc. where electrically live terminals and wires are existing. Therefore, only competent electricians shall be allowed to handle such equipment.
All the electrical equipment in the plant such as motors, starters, push buttons shall be well earthed to avoid electrical shocks in case of short-circuiting of the power anywhere. So also the entire plant shall be well earthed.
Spillage of oil, miscella etc. on the floor and, especially on the staircases, shall be avoided and in case of any such spillage, it shall be thoroughly cleaned immediately to avoid slipping of foot of the personnel in the plant.

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Mechanical Accidents

In a Solvent Extraction Plant, the oil is extracted from oilseeds or oilcakes by treating the same with normal hexane and then distilling of the hexane from the resulting solution of oil in hexane. The extracted material is also heated to vapourise the hexane. All the vapours of hexane from distillation and desolventisation are condensed and reutilised for extraction. Normal hexane, being a highly volatile and inflammable liquid, poses the greatest potential for hazard in the plant. The oil/fat extracted is also a source for fire hazard. So also is the oil-bearing raw material.

Therefore, certain very important precautions are taken in designing a Solvent Extraction Plant and operating the same as enumarated below:-
No naked fire is allowed in the vicinity of a solvent extraction plant. All the heating, necessary in the plant is carried out by only steam and not by naked fire or electrical fire, as the naked fire and electrical heating are not controllable below the ignition temperature of hexane and therefore, can cause the fire.
For the ignition to occur in a hexane atmosphere there must be a proper mixture of oxygen (air) and hexane as well as ignition temperature. Once the oxidation (burning) of hexane starts the reaction is highly exothermic and produces enough heat to continue the reaction (i.e. burning) and the fire quickly spreads. The reaction produces (mainly carbon dioxide) are released in great volumes creating the pressure inside the burning enclosures and the explosion results. Therefore, to avoid fire and/or explosion in a solvent plant it is necessary to see that the air and hexane vapours do not exist in explosive limits. The explosive limits for hexane and air are below 6.9% and above 1.2% hexane in air by volume. In a plant which is working normally, the atmosphere inside the equipment is full of saturated vapours of hexane containing negligible amount of air. And hence, it does not constitute a dangerous atmosphere. But, during the starting and stopping of a plant, the proportion of air inside the equipment is much higher and that may pose a potential hazard. Therefore, during this period it is necessary to ensure that no ignition temperature is reached in any part of the plant. A safe plant design shall take this into consideration.
While the atmosphere inside the equipment is free from hazard in a working plant, any leak of solvent vapours from the equipment constitutes a serious hazard. The leaking vapours meet with enough amount of atmospheric air just outside the leaky spot and can catch fire in case of ignition. Therefore, it is absolutely necessary to block all the leaks in a plant, not only to prevent hazards but also to reduce hexane loss. The potential leaky areas are:
 
•  Flanges not properly tightened
•  Damaged packings between the flanges.
•  Welding leaks due to inferior workmanship
•  Screw joints not properly tightening
•  Damaged mechanical seals
•  Pump glands
•  Glands of valves in process lines
It is good practice to take hydraulic test of the plant periodically to locate any such leaks and plug them.

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Accidents by Human Failure

In spite of all the precautions taken in designing a solvent extraction plant, an accident can occur due to what is called human failure. This is essentially due to the lethargy on the part of the operators to observe a few well established and simple safety rules and sidetrack the same to `SAVE' some work. Therefore, the following guidelines shall be strictly enforced in a solvent extraction plant to avoid accidents due to human failure:-
Putting hands and limbs into running machinery is a common mode of accidents. The operators of plants shall be strictly warned that no machine shall be run without the covering of moving parts in place. Many a times operators take out the guards and covers for maintenance or repairs, but do not replace them before starting the machine. This should strictly not be allowed.
The operators shall be strictly prohibited from taking any matches, candles, cigarettes, and naked flames in any form inside the solvent plant area, including preparatory section, bagging section and oil storage tanks. Warning signs in regard to the same shall be exhibited at such restricted areas.
The plant operators shall be thoroughly made to understand the potential hazards involved and their causes as explained under A and B above to evolve safety consciousness in them.
People who are not authorised to work in the solvent plant area shall not be allowed to enter there.
'NO SMOKING' signs shall be exhibited at as many spots as possible to repeatedly remind the people not to smoke and about the consequent fire hazard in case of smoking.
Many a times the plant personnel are tempted to `Dry Clean' their clothes using the hexane available in the plant. To avoid detection they do so in the electrical cabin which is the only enclosed room available for such clandestine activity. This is most dangerous to do as there are continuous electrical sparks in the panel board and the hexane vapours generated may get ignited. There are instances of electrical cabin blowing off with the personnel inside. The plant personnel must be thoroughly educated in this regard and the hazard involved must be impressed upon them. Using hexane for washing clothes shall be totally disallowed.
Normal-Hexane is a slightly toxic substance and continuous and heavy inhaling of hexane vapours can render a person `Drunk'. Therefore, no personnel shall enter the extractor or any other equipment in the plant when there are heavy hexane vapours. The equipment shall be properly desolventised before entering. In conclusion, it can be stated that if all the safety precautions enumerated above are diligently implemented, a solvent extraction plant can be as safe as or even safer then any other INDUSTRY.

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